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Fluorescence of Solids | Nature

THE following observations may be of interest in view of the present interest in problems of fluorescence of solids. Anthracene (I) in the solid state fluoresces blue with a high efficiency, the ...

Disproportionation-induced solid-state fluorescence in 6 ...

Upon heating or photoirradiation of 3 in the solid state, the fluorescence color gradually changed from bright blue to red. The solid-state fluorescence behavior 15 induced by disproportionation may serve as an example for guided molecular engineering, providing fascinating possibilities to tune materials for sensing, as well as optical and thermal recording applications. Experimental section ...

Fluorescence - Wikipedia

Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation.It is a form of luminescence.In most cases, the emitted light has a longer wavelength, and therefore lower energy, than the absorbed radiation.The most striking example of fluorescence occurs when the absorbed radiation is in the ultraviolet region of the spectrum, and thus invisible ...

The relationship between solid-state fluorescence ...

The solid-state fluorescence intensity of coumarin dyes depends on the substituents present at the 4- and 7-positions. 7-(Diethylamino)coumarins showed higher solid-state fluorescence quantum yield (Φ f (ss) = 0.29–0.40) than 7-aminocoumarins (0.01).In the case of julolydyl coumarins, a 4-methyltetramethyljulolydyl derivative also displayed high Φ f (ss) (0.34), this being greater than ...

SPR-Enhanced Fluorescence of Solid Organic Dye Films

This paper presents strong fluorescence of spin-coated fluorescent solid organic dye films (SODF) enhanced by surface plasmonic resonance (SPR). In order to manifest the influence of SPR effect on enhancement of organic dye (OD) fluorescence, the organic dye embedded Ag@SiO 2 fluorescent films were developed on the glass sheet substrate, in which Ag@SiO<sub>2</sub> nanoparticles were embedded ...

Solid Materials with Near‐Infrared‐Induced Fluorescence ...

Solid molecular materials modulating their luminescent properties upon irradiation are typically based on photochromic dyes. Despite these are potentially interesting for applications such as anticounterfeiting, bioimaging, optical data storage, and writable/erasable devices, key features are preventing their use in marketable products: the lack of straightforward strategies to obtain near ...

Effect of π-conjugation on solid-state fluorescence in ...

Contrarily, HTpT exhibits bright red solid-state fluorescence (λ em: 600 nm, Φ f: 22.7%) with a 200 nm Stokes shift. Steady-state fluorescence spectra, theoretical calculations, and X-ray diffraction analysis are performed to elucidate these different photo-physical properties. In addition, unlike most lysosomal targeting probes containing proton-binding amino or morpholine moieties, which ...

Single‐Benzene‐Based Solvatochromic Chromophores: Color ...

Single‐Benzene‐Based Solvatochromic Chromophores: Color‐Tunable and Bright Fluorescence in the Solid and Solution States Dr. Huijing Liu Key Laboratory of Applied Surface and Colloid Chemistry of, the Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an, 710062 P.R. China

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Color‐Tunable Solid‐State Fluorescence Emission from ...

Color‐Tunable Solid‐State Fluorescence Emission from Carbazole‐Based BODIPYs † Dr. Chihiro Maeda. Corresponding Author. E-mail address: cmaeda@okayama-u.ac.jp. Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama, 700-8530 Japan. Search for more papers by this author. Takumi Todaka. Division of Applied Chemistry ...

Fluorescent carbon dots in solid-state: From ...

C. Wang, J. Zhou, L. Lulu, Q. SongRapid visualization of latent fingerprints with color-tunable solid fluorescent carbon dots Part Part Syst Char, 35 (2018), p. 1700387 Google Scholar

Solid‐State Carbon Dots with Red Fluorescence and ...

Stable solid‐state red fluorescence from organosilane‐functionalized carbon dots (CDs) with sizes around 3 nm is reported for the first time. Meanwhile, a novel method is also first reported for the efficient construction of dual‐fluorescence morphologies. The quantum yield of these solid‐state CDs and their aqueous solution is 9.60 and 50.7%, respectively. The fluorescence lifetime is ...

Full-color fluorescent carbon quantum dots | Science Advances

The growing electron-withdrawing groups on the surface of CQDs that originated from acid reagents boost their photoluminescence wavelength red shift and raise their particle sizes, elucidating the...

Multicolor fluorescent polymeric hydrogels: colorfulness ...

Multicolor fluorescent polymeric hydrogels (MFPHs) are three‐dimensionally cross‐linked hydrophilic polymer networks with tunable emission color. Different from the classic fluorescent materials used primarily in dry solid states or solutions, MFPHs exist as highly water‐swollen quasi‐solid state and thus present many promising properties of both solid and solution, including tissue ...

Plug-and-Play Optical Materials from Fluorescent Dyes and ...

While dyes can be readily made with bright fluorescence of any color, those properties cannot be transferred to materials without losing their fluorescence and changing their color. It is more art than science to obtain specific optical properties from dyes in the solid state. The problem occurs when dyes pack together in solids to become electronically coupled, which impacts the vast majority ...

Use of Fluorescence In Situ Hybridization (FISH) in ...

Applications of fluorescence in situ hybridization (FISH) in genetic diagnostics in solid tumors on FFPE material: A—1p/19q probe: a-1 deletion of 1p32 locus, a-2 normal signal pattern (cell on the left) and deletion of 19q13 locus (cell on the right), a-3 normal signal pattern (Abbott Molecular), B—dual fusion probe: fusions and normal signals pattern of COL1A1 and PDGFB loci (ZytoVision ...

Full‐Color Emission Polymer Carbon Dots with Quench ...

To solve the aforementioned problems associated with obtaining full‐color emission PCDs, and to achieve longer fluorescence in the solid state, herein, we prepared full‐color PCDs showing concentration controlled emission with the QY of 18.9%, 8.44%, 5.54%, and 8.5% in accordance with the red shift of emission wavelength. The PCDs possess self‐quenching‐resistant SSF, exhibiting strong ...

Color‐Tunable Solid‐State Fluorescence Emission from ...

The fluorescence properties showed good correlation with the results of crystal‐packing analyses, and the dyes exhibited color‐tunable solid‐state fluorescence. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors.

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"Smart" fluorescent dyes change color in different solid ...

Such a two-color emission from different solid phases could be useful for sophisticated optoelectronic and sensor applications. The Japanese authors found that the substance emitted orange fluorescence when deposited as a thin film, but this color turned to green when the film was annealed, that is, kept at high temperature and cooled down again. Then they scratched the annealed film and found ...

Full‐Color Emission Polymer Carbon Dots with Quench ...

Full-Color Emission Polymer Carbon Dots with Quench-Resistant Solid-State Fluorescence Jieren Shao, Shoujun Zhu, Huiwen Liu, Yubin Song, Songyuan Tao, and Bai Yang* J. R. Shao, Dr. S. J. Zhu, H. W. Liu, Y. B. Song, S. Y. Tao, Prof. B. Yang State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University

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Chemists create the brightest-ever fluorescent materials

While there are currently more than 100,000 different fluorescent dyes available, almost none of these can be mixed and matched in predictable ways to create solid optical materials. Dyes tend to ...

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